Procédés et mécanique aux petites échelles PROMETHEE
Micro-objets déformables sous forçage hydrodynamique
Microfluidique et Procédés
Organisation des écoulements aux petites échelles
Thermodynamique des mélanges
Forces de surface: nano-films et comportements de parois
Séparations membranaires
suite...
Présentation
L’équipe PROcédés et MEcanique aux petiTes écHEllEs (PROMETHEE) développe des compétences marquées relevant aussi bien de la mécanique des milieux continus que du génie des procédés tout en combinant approche expérimentale et développement de théories et de modèles. L’originalité des études menées se décline selon plusieurs spécificités :
Echelle micro-nano d’observation et d’analyse qui évacue les problématiques liées à la turbulence (régime de Stokes) mais nécessite de considérer des aspects aux frontières de la discipline ;
Rôle prédominant des interfaces : interactions avec les parois solides à l’échelle nano (nano-tubes), interaction fluide-structure avec des membranes fluides ou polymérisée à l’échelle méso ;
Connexion avec les fluides complexes, la matière molle et les systèmes biologiques.
Sur le thème de la micro- et nano-fluidique, les objets d’étude, physico-chimiques (gouttes, capsules,…) et biologiques (vésicules, globules rouges,…), comprennent aussi les procédés intensifiés d’encapsulation et de vectorisation par microréacteur, thèmes en plein essor. L’équipe développe également des outils de caractérisation de l’organisation aux petites échelles comme le développement de simulations numériques pour rendre compte de la ségrégation obtenue au sein de milieux granulaires et la mise au point de méthode chimique de caractérisation des effets de micromélange (mélange à l’échelle moléculaire). A cela s’ajoute une activité de caractérisation et modélisation thermodynamique de milieux complexes.
Les outils numériques développés et mis en œuvre sont variés : intégrale de frontière, éléments finis, immersed boundary method, méthode Lattice Boltzman…
Carlos Baqueiro, Nelson Ibaseta, Pierrette Guichardon, Laurent Falk. INFLUENCE OF REAGENTS CHOICE (BUFFER, ACID AND INERT SALT) ON TRIIODIDE PRODUCTION IN THE VILLERMAUX-DUSHMAN METHOD APPLIED TO A STIRRED VESSEL. Chemical Engineering Research and Design, Elsevier, In press, 〈10.1016/j.cherd.2018.04.017〉. 〈hal-01771934〉 Plus de détails...
This work studies how deeply the reagents choice influences micromixing characterisation by the Villermaux-Dushman method, when applying it to a 1 litre stainless steel standard vessel with two baffles, stirred by an inclined blade turbine. For the first time, borate and phosphate buffer are compared on their use in the method. It is observed that triiodide production is higher when borate buffer is used. Moreover, perchloric acid leads to higher triiodide production than sulphuric acid, when injecting the same concentration of both acids. Finally, the influence of the ionic strength is also studied, since there has been a great deal of controversy about it over the last years. The results show that the ionic strength affects triiodide production, although relatively slightly. Advice concerning the choice of the reagents is given in conclusion.
Carlos Baqueiro, Nelson Ibaseta, Pierrette Guichardon, Laurent Falk. INFLUENCE OF REAGENTS CHOICE (BUFFER, ACID AND INERT SALT) ON TRIIODIDE PRODUCTION IN THE VILLERMAUX-DUSHMAN METHOD APPLIED TO A STIRRED VESSEL. Chemical Engineering Research and Design, Elsevier, In press, 〈10.1016/j.cherd.2018.04.017〉. 〈hal-01771934〉
Mustapha-Kamel Khelloufi, Etienne Loiseau, Marc Jaeger, Nicolas Molinari, Pascal Chanez, et al.. Spatiotemporal organization of cilia drives multiscale mucus swirls in model human bronchial epithelium. Scientific Reports, Nature Publishing Group, 2018, 8 (1), pp.2447. 〈10.1038/s41598-018-20882-4〉. 〈hal-01713302〉 Plus de détails...
Mucociliary clearance is a biomechanical mechanism of airway protection. It consists of the active transport along the bronchial tree of the mucus, a fluid propelled by the coordinated beating of a myriad of cilia on the epithelial surface of the respiratory tract. The physics of mucus transport is poorly understood because it involves complex phenomena such as long-range hydrodynamic interactions, active collective ciliary motion, and the complex rheology of mucus. We propose a quantitative physical analysis of the ciliary activity and mucus transport on a large panel of human bronchial cultures from control subjects, patients with asthma and chronic obstructive pulmonary disease obtained from endobronchial biopsies. Here we report on the existence of multiple ciliary domains with sizes ranging from the tens of a micron to the centimeter, where ciliary beats present a circular orientational order. These domains are associated with circular mucus flow patterns, whose size scales with the average cilia density. In these domains, we find that the radial increase of the ciliated cell density coupled with the increase in the orientational order of ciliary beats result in a net local force proportional to the mucus velocity. We propose a phenomenological physical model that supports our results.
Mustapha-Kamel Khelloufi, Etienne Loiseau, Marc Jaeger, Nicolas Molinari, Pascal Chanez, et al.. Spatiotemporal organization of cilia drives multiscale mucus swirls in model human bronchial epithelium. Scientific Reports, Nature Publishing Group, 2018, 8 (1), pp.2447. 〈10.1038/s41598-018-20882-4〉. 〈hal-01713302〉
Evelyne Neau, Christophe Nicolas, Laurent Avaullée. Extension of the group contribution NRTL-PRA EoS for the modeling of mixtures containing light gases and alcohols with water and salts. Fluid Phase Equilibria, Elsevier, 2018, 458, pp.194-210. 〈10.1016/j.fluid.2017.09.028〉. 〈hal-01703014〉 Plus de détails...
The offshore exploitation of petroleum fluids in normal conditions of pressure and temperature of transport and in presence of salt water is concerned with the prevention of gas hydrate formation, generally thanks to continuous injection of inhibitors, or punctual injection of methanol in start-up and shut-down operations. Hence, models of interest should provide both, satisfactory phase equilibrium estimations of hydrocarbon and alcohol mixtures with water and reliable predictions of their behavior in presence of salts.
Evelyne Neau, Christophe Nicolas, Laurent Avaullée. Extension of the group contribution NRTL-PRA EoS for the modeling of mixtures containing light gases and alcohols with water and salts. Fluid Phase Equilibria, Elsevier, 2018, 458, pp.194-210. 〈10.1016/j.fluid.2017.09.028〉. 〈hal-01703014〉
Evelyne Neau, Christophe Nicolas, Laurent Avaullée. Extension of the group contribution NRTL-PRA EoS for the modeling of mixtures containing light gases and alcohols with water and salts. Fluid Phase Equilibria, Elsevier, 2018, 458, pp.194-210. 〈10.1016/j.fluid.2017.09.028〉. 〈hal-01703014〉 Plus de détails...
The offshore exploitation of petroleum fluids in normal conditions of pressure and temperature of transport and in presence of salt water is concerned with the prevention of gas hydrate formation, generally thanks to continuous injection of inhibitors, or punctual injection of methanol in start-up and shut-down operations. Hence, models of interest should provide both, satisfactory phase equilibrium estimations of hydrocarbon and alcohol mixtures with water and reliable predictions of their behavior in presence of salts.
Evelyne Neau, Christophe Nicolas, Laurent Avaullée. Extension of the group contribution NRTL-PRA EoS for the modeling of mixtures containing light gases and alcohols with water and salts. Fluid Phase Equilibria, Elsevier, 2018, 458, pp.194-210. 〈10.1016/j.fluid.2017.09.028〉. 〈hal-01703014〉
An internal energy function of the mass density, the volumetric entropy and their gradients at n-order generates the representation of multi-gradient fluids. Thanks to Hamilton's principle, we obtain a thermodynamical form of the equation of motion which generalizes the case of perfect compressible fluids. First integrals of flows are extended cases of perfect compressible fluids. The equation of motion and the equation of energy are written for dissipative cases, and are compatible with the second law of thermodynamics.
Henri Gouin. Multi-gradient fluids. Ricerche di matematica, Springer Verlag, In press. 〈hal-01731201〉
10 Décembre 2014
- "On the Coupling of Membrane Transport to Hydrodynamics and Bulk Mass Transfer in Reverse Osmosis: Numerical Modeling and Experimental Studies" / Soutenance de thèse: Gustavo Henndel Lopes
Doctorant: Gustavo Henndel LOPES
Directrice de thèse: Pierrette GUICHARDON Co-Directeur de thèse: Nelson IBASETA
Date de soutenance: le 10 Décembre 2014 à 10h00, amphithéâtre 1 de l'École Centrale Marseille
Résumé: The prediction of the performance of pressure-driven membrane
separations, deeply affected by concentration polarization, would be an
important advance for process design and optimization. In this context,
the dimensionless coupled Navier-Stokes and solute conservation
equations are solved numerically for a steady laminar cross-flow
filtration. The two-dimensional flat channel consists of permeable walls
subject to solution-diffusion boundary conditions. The permeate flux,
the rejection rate and the retentate's flow rate, concentration and
pressure drop are determined locally. The simulations highlight the
influence of the membrane solute and solvent permeabilities on
concentration polarization and the non-asymptotic dependence of the
rejection rate on the applied pressure. The model is validated for
reverse osmosis and tight-nanofiltration plate-and-frame and
spiral-wound modules by comparison to experimental results from the
literature and from our own pilot desalination tests. Furthermore, a
bench-scale method enabling the determination of solute and solvent
permeabilities from osmotic-diffusive experiments is developed and
applied to reverse osmosis and nanofiltration membranes. The divergence
between the transport mechanisms engendered by pressure and by an
osmotic gradient is evidenced. The numerical model and the experimental
method are new promising tools with immediate applicability in the
membrane field.
Jury: Sébastien DÉON, Maître de conférences, Université de Franche-Comté (Rapporteur)
Pierrette GUICHARDON, Professeur des universités, École Centrale Marseille (Directrice de thèse)
Pierre HALDENWANG, Professeur des universités, Aix Marseille Université (Examinateur)
Nelson IBASETA, Maître de conférences, École Centrale Marseille (Codirecteur de thèse)
Alain LINÉ, Professeur des universités, Inst. Nat. de Sci. Appl. de Toulouse (Rapporteur)
Ana María URTIAGA, Profesora catedrática, Universidad de Cantabria (Examinatrice)
